Belite-Ye’elimite-Ferrite (BYF) cements have received increasing attention in view of their lower CO2 footprint and their interesting performances. This work deals with the effect of polycarboxylate superplasticizer (SP) on BYF cement paste. It was found that SP dosage must be low in order to avoid destabilization, and thus improve the resistance to bleeding and segregation. Also, the good affinity of polycarboxylate-based superplasticizer with cement surface improves the cement particles dispersion and causes a significant diminution of the yield stress during the low activity period. Furthermore, it is shown that SP causes a delay in the early age hydration, inducing a decrease in the compressive strength at early age while it increases them after 90 days.

For the purpose of fabricating electrically conductive composites via the fused filament fabrication (FFF) technique whose properties were compared with injection-moulded properties, poly(lactic acid) (PLA) and polycaprolactone (PCL) were mixed with different contents of graphene nanoplatelets (GNP). The wettability, morphological, rheological, thermal, mechanical, and electrical properties of the 3D-printed samples were investigated. The microstructural images showed the selective localization of the GNPs in the PCL nodules that are dispersed in the PLA phase. The electrical resistivity results using the four-probes method revealed that the injection-moulded samples are insulators, whereas the 3D-printed samples featuring the same graphene content are semiconductors. Varying the printing raster angles also exerted an influence on the electrical conductivity results. The electrical percolation threshold was found to be lower than 15 wt.%, whereas the rheological percolation threshold was found to be lower than 10 wt.%. Furthermore, the 20 wt.% and 25 wt.% GNP composites were able to connect an electrical circuit. An increase in the Young’s modulus was shown with the percentage of graphene. As a result, this work exhibited the potential of the FFF technique to fabricate biodegradable electrically conductive PLA-PCL-GNP composites that can be applicable in the electronic domain.

We study the crushing strength of brittle materials whose internal structure (e.g., mineral particles or grains) presents a layered arrangement reminiscent of sedimentary and metamorphic rocks. Taking a discrete-element approach, we probe the failure strength of circular-shaped samples intended to reproduce specific mineral configurations. To do so, assemblies of cells, products of a modified Voronoi tessellation, are joined in mechanically-stable layerings using a bonding law. The cells’ shape distribution allows us to set a level of inherent anisotropy to the material. Using a diametral point loading, and systematically changing the loading orientation with respect to the cells’ configuration, we characterize the failure strength of increasingly anisotropic structures. This approach lets us reproduce experimental observations regarding the shape of the failure strength curve, the Weibull modulus, failure patterns of rocks, and quantify the consumption of the fragmentation energy, and the induced anisotropies linked to the cell’s geometry and force transmission in the samples. Based on a fine description of geometrical and mechanical properties at the onset of failure, we develop a micromechanical breakdown of the crushing strength variability using an analytical decomposition of the stress tensor and the geometrical and force anisotropies. We can conclude that the origins of failure strength in anisotropic layered media rely on compensations of geometrical and mechanical anisotropies, as well as an increasing average radial force between minerals indistinctive of tensile or compressive components.